Synthesis, Thermal and Electrochemical Properties of Dipeptide Substituted Metallo-Phthalocyanine Complexes
DOI:
https://doi.org/10.5281/zenodo.14582512Keywords:
Phenylalanine, Phthalocyanine, Thermal analysis, Electrochemistry, Dipeptide, Metallo-phthalocyanineAbstract
A novel Tyrosine-Phenylalanine dipeptide substituted metallo phthalocyanine complexes was Synthesis, characterized, their thermal and electrochemical properties was established as the main purpose for this work. The dipeptide methyl (tert-butoxycarbonyl) tyrosyl-D-phenylalaninate (3) was synthesis through peptide coupling reaction of (tert-butoxycarbonyl) tyrosine (1), and phenylalanine (2) and it was reacted with 4-nitrophthalonitrile (4) to form dipeptide substituted phthalonitrile (5).
The dipeptide substituted phthalonitrile ligand undergo cyclotetramerization in the presence of metals salt of Co(II), Cr(III) and Ni(II) acetate in Dimethylformamide (DMF) at 150 °C to form Tyrosine- Phenylalanine dipeptide substituted phthalocyanine complexes of respective metals. The formation of these synthesized compounds was verified by melting point, FT-IR, UV-visible, 1H NMR and 13C NMR and mass spectroscopy techniques. Thermal properties were investigated by TGA and DTA analysis. Electrochemical measurements of phthalocyanine complexes were performed by Cyclic or Square wave voltammetry in DMF
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