Synthesis and Characterization of Nitrotetrasubstituted Metallophthalocyanine (Zn, Co, Ni, Cu) Derivatives
DOI:
https://doi.org/10.5281/zenodo.14582491Keywords:
Phthalocyanine, Nitrophthalocyanine, Zinc, Cobalt, Nickel, CopperAbstract
4-(2,4-dinitrophenoxy)phthalonitrile, 1, was prepared by the reaction of 4-hydroxyphthalonitrile and 1-chloro-2,4-dinitrobenzene in the presence of K2CO3. Zn(II), 2, metallophthalocyanine was synthesized by the reaction of phthalonitrile derivative with Zn(OAc)2 ·2H2O in quinoline. Co(II), 3, Ni(II), 4, and Cu(II), 5, metallophthalocyanine derivatives were synthesized by the reaction of phthalonitrile derivative 1 with CoCl2 ·6H2O, NiCl2·6H2O and CuCl2 salts in ethylene glycol, respectively. Compound 1 has been characterized by FT-IR and 1H-NMR spectroscopies. Metallophalocyanin compounds 2-5 have been characterized by the UV/Vis, and FT-IR spectroscopies.
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